Sterically-hindered Organosilicon Compounds Containing Cyclohexyl Groups. II. Hydrogenation of Phenylsilicon Compounds
نویسندگان
چکیده
منابع مشابه
Some highly sterically hindered organosilicon compounds
The chemistry of organometallic compounds with bulky ligands such as (Me3Si)3C(Tsi) or (Me2PhSI)3C(Tpsi) attached to a variety of metal centres is reviewed. The compounds Tsi2M (M = Zn, Cd, Hg) and the rare two co-ordinate TsiMn show exceptional thermal and hydrolytic stability. The corresponding alkylmetal halides form ring or cage structures. In a range of new boron compounds the structures o...
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Silathiazolidine and metalladithioacetals (M = Si, Ge) have been prepared by the interaction of dialkyldichloro- or bis(diethylamino)dialkylsilanes and -germanes with 3-[N-(2- thioethyl)]amino-propanamide (WR-2529) and [1-thioethyl-2-(1-naphtylmethyl)]-2- imidazoline. The study of these compounds in the field of chemical radioprotection has shown a notable decrease in the toxicity and a rather ...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1963
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.36.284